By Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Kunihito KOUMOTO, Nagoya University, Japan Nicola ROMEO, University of Parma,
Read or Download 5th FORUM ON NEW MATERIALS PART C Proceedings of the 5th Forum on New Materials, part of CIMTEC 2010-12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 13-18, 2010 PDF
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Extra info for 5th FORUM ON NEW MATERIALS PART C Proceedings of the 5th Forum on New Materials, part of CIMTEC 2010-12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 13-18, 2010
Thus, it is strongly suggested, as a possible mechanism, that the large decrease in the lattice thermal conductivity for Ba8-xEuxGa16Si30 with x=2 can be attributed to the increase in scattering of phonons by the thermal “rattling” motion of guest Eu atoms that interact with phonons of framework with lower frequency. Summary Polycrystalline silicon clathrate compounds with Ba8-xAxGa16Si30 (A=Sr, Eu; x=0, 1, 2) nominal compositions were prepared by a powder metallurgy technique. The high temperature thermoelectric properties were investigated and analyzed to elucidate the effects of guest substitutions on the electronic and thermal transport properties.
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For each sample, 10 data points were collected on each sample and the results were averaged together to obtain the composition of the films. The films on a silicon substrate were analyzed using three different accelerating voltages (8, 12, and 16 kV), and the StrataGem software package was used to determine the composition of the films. [18,19] Results and Discussion Preparation of Precursors. The synthesis procedure developed by Harris was used to prepare each of the precursors designed to form the nanolaminates targeted in this study.